A Textbook of Physical Chemistry for IIT JEE

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Table of Contents Introduction: Physical Chemistry 1. Measurements Measurements in Chemistry SI Units Problem Solving Mathematical Operations Additional Solved Examples Assignments 2. Mole Concept The Mole Atomic Mass Unit Volume Vs Mole Law of Mass Conservation Law of Multiple Proportions Law of Definite Proportions Gay Lussac?s Law and Avogadro?s Law Dalton?s Atomic Theory Atomic Number, Mass Number and Isotopes Molarity Mole Fraction Per Cent Concentrations Molality Equivalent Mass and Normality Stiochiometry: Quantitative Relations in Chemical Reactions Per Cent Composition and Empirical Formula Additional Solved Examples Assignments 3. Atomic Structure Fundamental Aspects Photoelectric Effect Particle and Wave Nature (Dual Nature) of Electron Heisenberg?s Uncertainty Principle Bohr?s Theory of H-atom Quantum Numbers Electronic Configuration Wave Mechanics (Quantum Mechanical Model of the Atom) Additional Solved Examples Assignments 4. Gaseous State Units Gas Laws The Kinetic-Molecular Theory of Gases Behaviour of Real Gases Critical Constants Boyle?s Temperature Collision Frequency and Mean Free Path Additional Solved Examples Assignments 5. Solutions and Colligative Properties Solutions Methods of Expressing Concentration of a Solution Van?t Hoff Factor ?I? and Colligative Properties Elevation in Boiling Point Depression in Freezing Point Osmosis and Osmotic Pressure Raoult?s Law (Vapour-Pressure Lowering of Solutions) Various Colligative Properties: Applications Additional Solved Examples Assignments 6. Kinetics Rate of Reaction Law of Mass Action and Rate Constant Rate Law, Molecularity and Order of Reaction Integrated Equation for Rate Constants of Different Ordered Reactions Experimental Determination of the Rate Constant Methods of Determination of the Order of a Reaction Effect of Temperature on Reaction Rate: Energy of Activation and Arrhenius Equation Mechanism of Reactions Additional Solved Examples Assignments 7. Chemical Equilibrium State of Equilibrium Law of Mass Action and Equilibrium Constant Using the Equilibrium Constant of Dissociation Types of Equilibria Factors that alter the Composition of an Equilibrium Mixture Thermodynamics of Chemical Equilibrium Additional Solved Examples Assignments 8. Thermodynamics Basic Concepts First Law of Thermodynamics Second Law of Thermodynamics Entropy. Free Energies Additional Solved Examples Assignments 9. Thermochemistry Thermochemistry Heat of Reaction Heat of Formation Heat of Combustion Heat of Neutralization Heat of Solution Bond EnergyHess?s Law of Constant Heat Summation Calorimetry Additional Solved Examples Assignments 10. Ionic Equilibria Acids and Bases pH-Scale Ostwald?s Dilution Law Buffers Common Ion Effect The Solubility Product Constant Hydrolysis Detection of the End Point: Indicators Acid-Base Titrations Additional Solved Examples Assignments 11. Electro Chemistry Cells Electrode Potential and Standard Electrode Potential Electrical Work, DG○, and Spontaneous Change Nernst Equation Various Types of Half-Cells Electrochemical Series EMF Measurement: Applications Batteries Electrolysis Quantitative Aspect of Electrolysis Commercial Electrolysis ? Processes Electrolytic Conductance Equivalent Conductance Kohlrauschs Law Applications of Conductance Measurements Corrosion Additional Solved Examples Assignments 12. Liquid State Phase Changes Comparison of Gases, Liquids and Solids Vapour Pressure Surface Tension Viscosity Additional Solved Examples Assignments 13. Surface Chemistry Colloidal System Classification Types of Solution Preparation Multimolecular and Macromolecular Colloids Properties of Colloids Charge on Colloidal Particles Coagulation and Hardy-Schulze Rule Protective Colloidal Sols and Gold Number Emulsions Applications of Colloidal Sols Adsorption Catalysts and Catalysis Activity and Selectivity Additional Solved Examples Assignments 14. Solid State Crystallography Space Lattice and Unit Cell Structure of Simple Ionic Compounds Packing and Structure of Crystals Crystal Defect Properties of Solids Additional Solved Examples Assignments