Advanced Organic Chemistry: Reactions, Mechanisms And Structure

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The book covers the three fundamental aspects of the study of organic chemistry--reactions, mechanisms and structure. Part One explores the structure of organic compounds, providing the necessary background for understanding mechanisms. Part Two discusses reactions and mechanisms. Organized by reaction type, each of these chapters discusses the basic mechanisms along with reactivity and orientation as well as the scope and mechanisms of each reaction.

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Jerry March is a professor in the Department of Chemistry at Adelphi University. Dr. March is the author of General Chemistry and Introduction to General, Organic and Biochemistry. Dr. March received his doctorate in organic chemistry from Pennsylvania State University. Table of Contents Localized Chemical Bonding Delocalized Chemical Bonding Bonding Weaker than Covalent Stereochemistry Carbocations, Carbanions, Free Radicals, Carbenes, and Nitrenes Mechanisms and Methods of Determining Them Photochemistry Acids and Bases Effects of Structure on Reactivity Aliphatic Nucleophilic Substitution Aromatic Electrophilic Substitution Aliphatic Electrophilic Substitution Aromatic Nucleophilic Substitution Free-Radical Substitution Addition to Carbon-Carbon Multiple Bonds Addition to Carbon-Hetero Multiple Bonds Eliminations Rearrangements Oxidations and Reductions Appendices Indexes